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991.
992.
The use of coal fly ash as a fluoride retention additive has been studied as a way of treating flue gas desulphurisation (FGD) gypsum for its disposal in landfills. With this end leaching studies following the standard EN-12457-4 [Characterization of waste- Leaching-Compliance test for leaching of granular waste materials and sludges - Part 4: One stage batch test at a liquid to solid ratio of 10l/kg for materials with particle size below 10mm (without or with size reduction)] have been performed on FGD gypsum samples treated with different proportions of fly ash (0.1-100%). It was found that the fluoride leachable content in FGD gypsum was reduced in the range 1-55%, depending on the fly ash proportion added to FGD gypsum. High levels of fluoride leaching reduction (close to 40%) were achieved even at relatively low fly ash additions (5%). So, low fly ash incorporations assure the characterization of this by-product as a waste acceptable at landfills for non-hazardous wastes according to the Council Decision 2003/33/EC [Council Decision 2003/33/EC of 19 December 2002 establishing criteria and procedures for the acceptance of waste at landfills pursuant to Article 16 of and Annex II to Directive 1999/31/EC] on waste disposal. Furthermore, the effectiveness of the proposed FGD gypsum stabilization method was also studied in column leaching systems, proving its good performance in simulated conditions of disposal. In such conditions a fluoride leaching reduction value slightly higher than 25% was displayed for a fly ash added amount of 5%. 相似文献
993.
随着环境保护标准的日益严格、公众环境权益要求的不断提高,石油企业实施绿色采购已成为实施节能减排、提高竞争能力、实现又快又好发展的重要途径;这也是建设环境友好型、资源节约型企业的重要内容。石油企业应从推行物资供应各环节监管、实施物资生命周期全过程评估、加强物资产品供应商管理、强化物资流通信息化建设等方面,建立完善的企业绿色采购管理体系。 相似文献
994.
995.
Rheology of Lyocell Solutions from Different Cellulose Sources 总被引:4,自引:0,他引:4
B. J. Collier M. Dever S. Petrovan J. R. Collier Z. Li X. Wei 《Journal of Polymers and the Environment》2000,8(3):151-154
Rheological measurements were used to characterize the behavior of lyocell solutions, i.e., cellulose dissolved in N-methymorpholine-N-oxide. Cellulose sources included dissolving pulp, kraft pulp, sugar cane fibers, and kenaf fibers. The dominance of viscous behavior, G values, over elastic behavior, G values, is affected by cellulose concentration and molecular weight. At lower concentrations and degrees of polymerization (DP), dissolving pulp solutions show viscous, inelastic behavior at low frequencies. At higher concentration and DP, dissolving pulp solutions are more elastic at higher frequencies. Solutions prepared with kenaf and sugar cane fibers show similar properties to those using pure dissolving pulp, and comparisons suggest the molecular weight and/or the presence of other substances such as lignin in the cellulose from these alternative sources affect the rheology. 相似文献
996.
Otero XL Vidal-Torrado P Calvo de Anta RM Macías F 《Environmental pollution (Barking, Essex : 1987)》2005,136(1):119-134
The trace elements present at highest concentrations were Cr and Zn, which probably originated from the dumping of effluent from a tanning factory. High proportions of these two elements were associated with the residual fraction. Biodeposits and sediments showed high concentrations of Cd and Pb in the reactive fraction, with a high proportion of the concentration in the reactive fraction being associated with carbonates. Nickel showed a higher degree of pyritization than the previous elements, although most of the Ni was associated with the residual and reactive fractions. Arsenic, Hg and Cu showed high degrees of pyritization, particularly below a depth of 5 cm. The results demonstrate that those elements with a high degree of pyritization may be released into the water through oxidation of the metal sulphides that they form when in suspension in oxic sea water, with the subsequent risk of increased bioavailability to benthic fauna. 相似文献
997.
In the present study, we investigated to find novel ligands for low molecular weight environmental toxin, microcystin-LR (MC-LR) by using phage display technology. Two random libraries, displaying linear 12-mer peptides and cyclic 7-mer peptides, were screened against the immobilized target respectively. After three rounds of panning, phage clones that recognized microcystin-LR specifically were obtained from both the linear and the constrained libraries, proved by enzyme-linked immumosorbent assays and immunoprecipitation assays. DNA sequencing indicated that peptides displayed on some of the selected clones shared consensus sequences. Compared with traditional methods, this approach provided a cheaper and more rapid alternative to screen specific ligands for microcystin-LR. Moreover, since it is rather difficult to take small molecules as targets of phage display libraries, the success of this experiment expanded the applications of phage display technology, and provided a new avenue to study environmental small molecular toxins. 相似文献
998.
Stocki TJ Blanchard X D'Amours R Ungar RK Fontaine JP Sohier M Bean M Taffary T Racine J Tracy BL Brachet G Jean M Meyerhof D 《Journal of environmental radioactivity》2005,80(3):305-326
In preparation for verification of the Comprehensive Nuclear-Test-Ban-Treaty, automated radioxenon monitoring is performed in two distinctive environments: Ottawa and Tahiti. These sites are monitored with SPALAX (Systeme de Prelevement d'air Automatique en Ligne avec l'Analyse des radioXenons) technology, which automatically extracts radioxenon from the atmosphere and measures the activity concentrations of (131m,133m,133,135)Xe. The resulting isotopic concentrations can be useful to discern nuclear explosions from nuclear industry xenon emissions. Ambient radon background, which may adversely impact analyser sensitivity, is discussed. Upper concentration limits are reported for the apparently radioxenon free Tahiti environment. Ottawa has a complex radioxenon background due to proximity to nuclear reactors and medical isotope facilities. Meteorological models suggest that, depending on the wind direction, the radioxenon detected in Ottawa can be characteristic of the normal radioxenon background in the Eastern United States, Europe, and Japan or distinctive due to medical isotope production. 相似文献
999.
1000.
T. Stoichev D. Amouroux M. Monperrus D. Point E. Tessier G. Bareille O. F. X. Donard 《Chemistry and Ecology》2006,22(2):137-148
Surface waters were collected in the River Adour estuary (south-western France) during different sampling periods from 1998 to 2001 in order to investigate the phase distribution and speciation of methylmercury (MeHg+). Although a high variability is observed, significant higher average concentrations of total MeHg+ (dissolved and particulate) are measured during the warm seasons, at 4.40±8.18 pM and 3.90±1.87 pM for July 1998 and September 1999, compared with the winter seasons, with concentrations at 0.99±2.85 pM and 1.00±1.75 pM for February 1998 and February 2001, respectively (one-tailed t-test, P=0.01). The seasonal variations are explained with enhanced bacterial activity during summer and sedimentation/resuspension phenomena. Additionally, signi-ficant longitudinal variations of the MeHg+ concentrations are observed. The highest levels in both dissolved and particulate fractions are found within the downstream urban estuarine area. This can be explained by the high methylation potential of the sediments, but direct anthropogenic inputs of MeHg+ from specific discharge points cannot be neglected. Biogeochemical factors like phytoplankton biomass and salinity also show a relationship with MeHg+ partitioning in the surface waters of the Adour estuary. 相似文献